CHINESE JOURNAL OF ENERGETIC MATERIALS
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超声检测方法研究HMX及TATB基PBX的热循环性能
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1.中国工程物理研究院化工材料研究所, 四川 绵阳 621999;2.北京理工大学先进加工技术国防重点学科实验室, 北京 100081

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国家自然科学基金资助(11702262)


Thermal Cycling Properties of HMX- and TATB- Based PBX on Ultrasonic Testing Method
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1.Institute of Chemical Materials,CAEP,Mianyang 621999,China;2.Key Laboratory of Fundamental Science for Advanced Machining,Beijing Institute of Technology, Beijing 100081,China

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    摘要:

    为了获得奥克托今(HMX)及三氨基三硝基苯(TATB)基高聚物黏结炸药(PBX)热循环性能,在-40~75 ℃条件下对HMX及TATB基PBX进行热循环试验,采用超声回波法对分别经历3N个(N=0,1,2,…,9)热循环周期的炸药试件的纵、横波声速进行了测试,通过弹性模量和泊松比的超声测量方法计算得到动弹性模量(杨氏模量、剪切模量)和动泊松比,通过拉伸力学性能试验对静弹性模量进行了测试,计算得到动静弹性模量比。结果在热循环试验过程中,随着周期增加,HMX基PBX密度降低且降低速率逐步平缓,TATB基PBX密度呈先降低并速率放缓后略微回升的趋势,HMX及TATB基PBX纵波声速、横波声速、动杨氏模量、动剪切模量的变化趋势与其密度变化趋势一致,动泊松比基本不变,纵、横波声速与密度具有正相关的线性关系,静弹性模量先降低再升高,动静弹性模量比先升高再降低,静弹性模量和动静弹性模量比的变化拐点HMX基PBX在第15个热循环周期,TATB基PBX在第21个热循环周期。说明PBX热循环损伤量与密度变化和内部微损伤密切相关,超声纵、横波声速可定量评价PBX热循环试验中的热疲劳损伤;PBX动、静态弹性模量的差别是由PBX的结构特征所决定的;PBX动、静态弹性模量的变化趋势由微观机制控制,内在因素包括PBX内部的微裂隙、孔隙黏结剂流动。

    Abstract:

    In order to obtain the thermal cycling properties of octogen(HMX) and triaminotrinitrobenzene(TATB) based polymer bonded explosive (PBX) , the thermal cycling tests of HMX- and TATB-based PBX were carried out under the condition of -40—75 ℃. P-wave and S-wave velocity of explosive specimens with 3N N=0,1,2,…,9) cycles were measured by ultrasonic echo method. The dynamic elastic modulus (Young"s modulus, shear modulus) and dynamic Poisson"s ratio were calculated by ultrasonic measurement method. The static elastic modulus was measured directly through the tensile property test, while the ratio of dynamic and static elastic modulus was calculated. Results show that the density of HMX-based PBX decreases and later the decrease rate slows down with the increase of the cycle number during the thermal cycling test. The density of TATB-based PBX decreases first, then the decrease rate slows down, and finally has a slight upward trend. The change trend of P-wave velocity, S-wave velocity and dynamic elastic modulus of HMX- and TATB-based PBX are consistent with the change trend of their density respectively. Their corresponding dynamic Poisson"s ratio is basically unchanged. There is a positive linear relationship between P-wave , S-wave velocity and its density. The static elastic modulus first decreases and then increases, the dynamic and static elastic modulus first increases and then decreases, where the inflexion point of HMX-based PBX is in its 15st thermal cycle, and that of TATB-based PBX is in its 21st thermal cycle. The results show that the damage quantity of PBX during thermal cycling is closely related to its density change and internal micro damage. All these phenomenon demonstrate that the ultrasonic longitudinal and shear wave velocities can be used to quantitatively evaluate the thermal fatigue damage of PBX in thermal cycling test. The change trend of the dynamic and static elastic modulus of PBX is related to its micro structure evolution including internal micro-cracks and binder flow in micro-pores.

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引用本文

程垄,徐尧,李丽,等.超声检测方法研究HMX及TATB基PBX的热循环性能[J].含能材料, 2020, 28(11):1095-1101. DOI:10.11943/CJEM2019292.
CHENG Long, XU Yao, LI Li, et al. Thermal Cycling Properties of HMX- and TATB- Based PBX on Ultrasonic Testing Method[J]. Chinese Journal of Energetic Materials, 2020, 28(11):1095-1101. DOI:10.11943/CJEM2019292.

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  • 收稿日期: 2019-11-15
  • 最后修改日期: 2020-07-07
  • 录用日期: 2020-01-14
  • 在线发布日期: 2020-06-23
  • 出版日期: 2020-11-25