CHINESE JOURNAL OF ENERGETIC MATERIALS
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FOX-7基浇注型PBX安全性能
作者:
作者单位:

中国工程物理研究院化工材料研究所

作者简介:

谢虓(1986-),男,助理研究员,主要从事混合炸药配方设计研究。e-mail:3s-xiexiao@caep.cn

通讯作者:

郑保辉(1985-),男,副研究员,主要从事高安全炸药设计与应用研究。e-mail:zhengbaohui@caep.cn

基金项目:

国家自然科学基金 11702269国家自然科学基金(11702269)


Safety Performance of FOX-7 Based Casting PBX
Author:
Affiliation:

Institute of Chemical Materials, CAEP, Mianyang 621999, China

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    摘要:

    为了提升奥克托今(HMX)为基的浇注型高聚物粘结炸药(Polymer Bonded Explosive,PBX)的安全性能,在配方中引入部分1,1-二氨基-2,2-二硝基乙烯(FOX-7)替换HMX,研究了FOX-7对配方的热安定性、机械感度、冲击波感度、静电火花感度等安全性能的影响规律。结果表明,在引入FOX-7后,与HMX基浇注型PBX配方GO-1相比,配方GOXL-A的摩擦感度降低;在快速烤燃、慢速烤燃试验中的响应时间分别延长了58.8%、18.5%,并通过了升温速率为3.3 ℃·h-1的极不敏感物质(EIS)缓慢升温试验考核;其冲击波感度显著降低,隔板厚度(L50)较GO-1降低了15.7%,50%临界起爆压力(p50)提升了9.5%; 其静电火花感度显著降低,50%发火电压(V50)与50%发火能量(E50)分别提升65.3%和187.5%。

    Abstract:

    In order to improve the safety performance of cyclotetramethylenetetranitramine (HMX) based cast polymer bonded explosive (PBX), a certain amount of 1,1-diamino-2,2-dinitroethylene (FOX-7) was substituted for HMX in the formulation. The influence of FOX-7 on the thermal stability, mechanical sensitivity, shock wave sensitivity and electrostatic spark sensitivity of the formulation was studied. The friction sensitivity of the formulation GOXL-A was lower than that of the HMX based cast PBX formulation GO-1 after the introduction of FOX-7. The response time in the fast cook-off and slow cook-off tests was delayed by 58.8% and 18.5%, respectively. The formulation had passed the EIS slow cook-off test with a heating rate of 3.3 ℃·h-1. The shock wave sensitivity was significantly reduced. The separator thickness (L50) was reduced by 15.7% compared with GO-1, and the 50% critical detonation pressure (p50) was increased by 9.5%. Its static spark sensitivity is significantly reduced. The 50% ignition voltage (V50) and 50% ignition energy (E50) increased by 65.3% and 187.5%, respectively.

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引用本文

谢虓,王述存,黄川,等. FOX-7基浇注型PBX安全性能[J].含能材料, 2019, 27(11):942-948. DOI:10.11943/CJEM2019167.
XIE Xiao, WANG Shu-cun, HUANG Chuan, et al. Safety Performance of FOX-7 Based Casting PBX[J]. Chinese Journal of Energetic Materials, 2019, 27(11):942-948. DOI:10.11943/CJEM2019167.

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历史
  • 收稿日期: 2019-06-13
  • 最后修改日期: 2019-07-07
  • 录用日期: 2019-08-15
  • 在线发布日期: 2019-11-27
  • 出版日期: 2019-11-25