CHINESE JOURNAL OF ENERGETIC MATERIALS
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自然温度环境贮存固体推进剂的老化等效温度研究
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航天化学动力技术重点实验室,湖北航天化学技术研究所

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Research on Aging Equivalent Temperature of Solid Propellants Stored at Natural Cycle Temperature
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Science and Technology on Aerospace Chemical Power Laboratory, Hubei Institute of Aerospace Chemotechnology, Xiangyang, 441003, China

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    摘要:

    采用传统方法评估自然环境贮存固体推进剂的老化,需要详细、长期的环境温度数据,应用受到很大的局限,为了解决这个问题,根据自然温度季节、昼夜变化规律,以及气温的地域分布的特点,基于月均气温数据得到温度季节、昼夜变化模型的各项参数,建立了一个基于月均气温的老化等效温度计算模型,用于评估自然温度贮存固体推进剂的老化效应。应用本模型计算了:端羟基聚丁二烯(HTPB)、硝酸酯增塑聚醚NEPE、复合改性双基(CMDB)三类典型固体推进剂在不同地区的老化等效温度。结果表明,老化等效温度显著大于年均气温,季节温差越大,差异越明显。固体推进剂的老化活化能越大,等效温度越向最大月均气温靠近,与年均气温的差异也越大。

    Abstract:

    Conventional methods for evaluating aging effects of solid propellants stored at natural temperature need long-term (at least 10 years) and detailed (at least daily) environment temperature data. It is very difficult or expensive to access those data in storage places. Even if the data has been obtained, it would be a very heavy workload to process them. A novel method has been established to substitute the conventional methods limited by data acquisition and processing. The method is based on monthly average temperature data. According to seasonal and diurnal variation models of natural temperature, the parameters of these models have been calculated from monthly average temperature data and local climate characteristics. Therefore, the aging equivalent temperature could be evaluated, and the natural temperature aging effects could be predicated. This method is simpler than conventional method in data processing. And the required temperature data of the method can be easily obtained through public ways. Aging equivalent temperatures of three typical solid propellants ((hydroxyl-terminated polybutadiene(HTPB), nitrate ester plasticized polyether (NEPE), composite modified double-base(CMDB)) stored in four typical regions was calculated by the novel method. Results show that the aging equivalent temperature is much higher than the annual average temperature. The difference between the aging equivalent temperature and the annual average temperature increases with the increase of the annual temperature range. As the aging activation energy of solid propellant increases, the aging equivalent temperature approaches the maximum monthly average temperature, and the difference between the equivalent temperature and the annual average temperature becomes larger.

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引用本文

池旭辉.自然温度环境贮存固体推进剂的老化等效温度研究[J].含能材料, 2019, 27(12):984-990. DOI:10.11943/CJEM2019099.
CHI Xu-hui. Research on Aging Equivalent Temperature of Solid Propellants Stored at Natural Cycle Temperature[J]. Chinese Journal of Energetic Materials, 2019, 27(12):984-990. DOI:10.11943/CJEM2019099.

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历史
  • 收稿日期: 2019-04-14
  • 最后修改日期: 2019-08-16
  • 录用日期: 2019-07-05
  • 在线发布日期: 2019-08-14
  • 出版日期: 2019-12-25