CHINESE JOURNAL OF ENERGETIC MATERIALS
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布氏压力计法评估炸药寿命的判据研究
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中国工程物理研究院化工材料研究所

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总装专项项目 989900709006总装专项项目(989900709006)


Explosive Life Evaluation Criterion by Burdon Method
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Institute of Chemical Materials, CAEP, Mianyang 621999, China

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    摘要:

    针对布氏压力计法评估炸药贮存寿命的判据问题,分别以0.05%和0.1%分解深度为终点指标,按照Berthelot方程进行线性回归,获得了32种炸药在不同温度(25~50 ℃)下的贮存寿命比对结果,发现存在两种情况:(1)对于大多数炸药,同一温度下,以0.05%分解深度为终点判据预估的贮存寿命小于以0.1%分解深度预估的贮存寿命,但却会出现以前者评估出的贮存寿命超短的现象;(2)对于极少数炸药,接近室温时,同一温度下以0.05%分解深度为终点判据预估的贮存寿命大于以0.1%分解深度预估的贮存寿命,但随着温度的升高,以0.05%分解深度预估的贮存寿命又重新小于以0.1%分解深度预估的贮存寿命。产生差异的原因在于,各温度下所选用的数据点是否均处于炸药等速分解期内。结果表明,以炸药处于等速分解期时的分解深度作为布氏压力计法评估炸药贮存寿命的终点判据更具有科学意义。

    Abstract:

    Aiming at the criterion of evaluating the shelf life of explosives by Bourdon method, the decomposition depths of 0.05% and 0.1% were used as the end points of life. The comparison results of storage life of 32 kinds of explosives at 25-50 ℃ were obtained by linear regression based on Berthelot equation. Two cases were found: 1) For most explosives, the estimated storage life at the same temperature that obtained by taking 0.05% decomposition depth as the end point was less than the estimated shelf life that obtained by taking 0.1% decomposition depth as the end point, but sometimes the estimated shelf life by the former would be extremely short; 2) For very few explosives, the estimated shelf life with 0.05% decomposition depth as the end point was greater than the estimated shelf life estimated at 0.1% decomposition depth at room temperature. However, as the temperature increased, the shelf life estimated by the 0.05% decomposition depth was again less than the estimated shelf life of 0.1% decomposition depth. Whether the selected experimental data points at each temperature are in the isokinetic decomposition period of the explosive is the reason for the difference. Results show that it is more scientific to use the decomposition depth of explosives in the isokinetic decomposition period as the end point criterion for evaluating the shelf life by Bourdon method.

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陈捷,熊鹰,睢贺良,等.布氏压力计法评估炸药寿命的判据研究[J].含能材料, 2019, 27(12):998-1003. DOI:10.11943/CJEM2019015.
CHEN Jie, XIONG Ying, SUI He-liang, et al. Explosive Life Evaluation Criterion by Burdon Method[J]. Chinese Journal of Energetic Materials, 2019, 27(12):998-1003. DOI:10.11943/CJEM2019015.

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  • 收稿日期: 2019-01-18
  • 最后修改日期: 2019-06-24
  • 录用日期: 2019-05-30
  • 在线发布日期: 2019-06-18
  • 出版日期: 2019-12-25