Seven metal salts based on the 1-(1H-1, 2, 4-triazole-3-yl) -1H-tetrazole were synthesized firstly by using the reaction with related hydroxide or carbonate. They are characterized by using EA, IR, NMR technologies. And X-ray single crystals of five metal salts were obtained. The thermal stability of the metal salts was studied by DSC. Most of them have good thermal stability after the water molecular was lost, and the decomposition temperature of lithium salts is highest with a value of 258 ℃. The enthalpy of formation was calculated by the isometric reaction method. The enthalpy of formation of two metal salts are higher than 1000 kJ·mol^-1. The detonation performance was estimated by using EXPLO5 software, and the impact sensitivity and friction sensitivity were tested. The results show that these metal salt are insensitive energetic materials.