CHINESE JOURNAL OF ENERGETIC MATERIALS
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Kooij方法预估固体火箭发动机中丁羟包覆层老化寿命
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1.陆军工程大学石家庄校区;2.981部队

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国家自然科学基金资助项目(51575523)


Storage Lifetime Prediction of HTPB Coating in Solid Rocket Motor Based on Kooij Method
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1.Shijiazhuang Campus, Army Engineering University,Shijiazhuang 050003,China;2.981 Forces,Wuhan 432200,China

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    摘要:

    为了准确地预估固体火箭发动机中丁羟包覆层的贮存寿命,开展了50,60,70 ℃和80 ℃时的加速老化试验,用对数模型、幂函数模型和指数模型研究了丁羟包覆层的最大延伸率随贮存时间的变化。选取Kooij方程作为丁羟包覆层的老化模型,预估了试样的常温贮存寿命。结果表明,α = 0.4时的幂函数模型能描述最大延伸率随时间的变化规律。所得老化反应的表观活化能约为29 kJ·mol-1,远小于60 kJ·mol-1,表示在50~80 ℃下进行的老化反应易于发生。以最大延伸率下降50%为失效准则,预估丁羟包覆层的常温贮存寿命为15.62年,能满足包覆层的老化性能要求。

    Abstract:

    To accurately predict the storage life of hydroxyl-terminated polybutadiene(HTPB)coating in solid rocket motor, accelerated aging tests at 50, 60, 70 ℃ and 80 ℃ were carried out. Logarithmic model, power function model and exponential model were used to study the maximum elongation of HTPB coating with storage time. Kooij equation was regarded as the aging model, and the storage life of HTPB coating at normal temperature was predicted. Results show that the power function model with α = 0.4 can describe the variation law of maximum elongation with time. The apparent activation energy of the aging reaction obtained is 29 kJ mol-1 approximately, which is far less than 60 kJ mol-1, revealing that the aging reaction during 50 ℃ to 80 ℃ is easy to occur. Taking the maximum elongation decrease of 50% as the failure criterion, the storage life of the estimated HTPB coating at normal temperature is 15.62 years, which can meet the aging performance requirements of the coating.

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引用本文

李科,郑坚,支建庄,等. Kooij方法预估固体火箭发动机中丁羟包覆层老化寿命[J].含能材料, 2018, 26(9):739-743. DOI:10.11943/CJEM2018035.
LI Ke, ZHENG Jian, ZHI Jian-zhuang, et al. Storage Lifetime Prediction of HTPB Coating in Solid Rocket Motor Based on Kooij Method[J]. Chinese Journal of Energetic Materials, 2018, 26(9):739-743. DOI:10.11943/CJEM2018035.

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历史
  • 收稿日期: 2018-02-02
  • 最后修改日期: 2018-05-08
  • 录用日期: 2018-03-30
  • 在线发布日期: 2018-05-04
  • 出版日期: 2018-09-20