CHINESE JOURNAL OF ENERGETIC MATERIALS
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DNAN/HMX熔铸炸药的流变特性
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1.西安近代化学研究所,陕西 西安710065;2.北京理工大学爆炸科学与技术国家重点实验室,北京 100081

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国家自然科学基金(11472252;11572295),军科委国防科技创新基金(1300013)


Rheological Properties of DNAN/HMX Melt-cast Explosives
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1.Xi′an Modern Chemistry Research Institute, Xi′an 710065, China;2.State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China

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    摘要:

    为了探索奥克托今(HMX)固含量、体系温度、HMX粒度、HMX颗粒级配及功能助剂等对2,4-二硝基苯甲醚(DNAN)/ HMX悬浮液流变性的影响规律,采用数字粘度仪,研究了不同物料状态下DNAN/HMX悬浮体系的表观粘度。结果表明:当HMX固含量为3%时,悬浮液呈现牛顿流体特性;HMX固含量为12%~30%时,该悬浮液表观粘度可用Ostwald-deWaele模型进行描述,非牛顿指数n值从0.842降低到0.374。95~116 ℃时,温度对表观粘度的影响可以用Arrhenius方程描述,活化能Ea从25.97 kJ·mol-1增加到30.17 kJ·mol-1。表观粘度随着粒度的增大而降低,当粒度为999.5 μm与粒度为132.6 μm的颗粒级配比为2:1时,表观粘度达到最小值,且固含量可达80%。功能助剂N-甲基-4-硝基苯胺(MNA)、三-(β氯乙基)磷酸酯(CEF)降低了悬浮液的表观粘度,而脱水山梨醇单硬脂酸酯聚氧乙烯醚(吐温60)、微晶蜡-80(MV80)、乙酸丁酸纤维素(CAB)、热塑性聚氨酯-5702(TPU5702)提高了悬浮液的表观粘度。

    Abstract:

    To explore the influence rule of octogen (HMX) solid content, system temperature, HMX particle size, HMX particle gradation and functional additives etc.on the rheological properties of 2, 4-dinitroanisole (DNAN)/HMX suspensions, the apparent viscosity of DNAN/HMX suspensions under different material state conditions was investigated by a digital viscometer.Results show that the suspension presents Newtonian fluid characteristics when the solid content is 3%.Apparent viscosity of the suspension can be described with Ostwald-deWaele model when the HMX solid content is 12%-30%, and the value of nonNewton index n is decreased from 0.842 to 0.374.The influence of temperture on the apparent viscosity can be described by the Arrhenius equation when the temperture is in the range of 95-116℃, and the activation energy Ea increases from 25.97 kJ·mol-1 to 30.17 kJ·mol-1.The apparent viscosity decrases as the particle size increases.When the particle gradation ratio of 999.5 μm particle size to 132.6 μm is 2:1, the apparent viscosity reaches the minimum and the solid content is up to 80%.Functional additives N-methyl-4-nitroaniline (MNA) and tri (β chloroethyl) phosphate (CEF) make the apparent viscosity of the suspensions decrease, while dehydrated sorbitol monostearate polyoxyethylene ether (Tween 60), microcrystalline wax-80(MV80), cellulose acetate butyrate (CAB), and thermoplastic polyurethane-5720(TPU 5720) make the the apparent viscosity of the suspensions increase.

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引用本文

蒙君煚,周霖,金大勇,等. DNAN/HMX熔铸炸药的流变特性[J].含能材料, 2018, 26(8):677-685. DOI:10.11943/CJEM2017374.
MENG Jun-jiong, ZHOU Lin, JIN Da-yong, et al. Rheological Properties of DNAN/HMX Melt-cast Explosives[J]. Chinese Journal of Energetic Materials, 2018, 26(8):677-685. DOI:10.11943/CJEM2017374.

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历史
  • 收稿日期: 2017-12-01
  • 最后修改日期: 2018-05-09
  • 录用日期: 2018-03-07
  • 在线发布日期: 2018-04-28
  • 出版日期: 2018-08-23