CHINESE JOURNAL OF ENERGETIC MATERIALS
+高级检索
高温自蔓延反应合成功能材料的研究进展
作者:
作者单位:

(1. 西北工业大学燃烧、热结构与内流场重点实验室, 陕西 西安 710072; 2. 西安北方惠安化学工业有限公司, 陕西 西安 710302)

作者简介:

左蓓璘(1986-),女,工程师,主要从事含能材料的燃烧机理研究。e-mail: 549379167@qq.com 通信联系人: 严启龙(1983-),男,教授,主要从事含能材料制备及表征。e-mail: qilongyan@nwpu.edu.cn

通讯作者:

严启龙(1983-),男,教授,主要从事含能材料制备及表征。e-mail: qilongyan@nwpu.edu.cn

基金项目:

国家自然科学基金面上项目(51776176)


Recent Progress on the Functional Materials Synthesized by High Temperature Self-Propagating Reactions
Author:
Affiliation:

(1. Science and Technology on Combustion, Thermostructure, and Internal Flow Laboratory, Northwestern Polytechnical University, Xi′an 710072, China; 2. Xi′an North Huian Chemical Industry Co., Ltd, Xi′an 710302, China)

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
    摘要:

    简要总结了自蔓延高温反应(SHS)的国内外发展过程。从SHS前驱体元素体系的组成及SHS产物的应用方向(粉体功能材料、陶瓷材料、涂层材料等)进行了分类阐述, 着重分析了未来含能材料在SHS方面的应用。其次, 重点分析了适用于不同应用方向SHS材料的点火机制、反应机制、热力学和动力学等理论分析, 在此基础上提出绝热温度不是SHS反应唯一判据的新观点。最后, 介绍了自蔓延高温反应的燃烧机理, 阐明了反应物粒径、球磨参数、反应物压坯压力等工艺参数对SHS反应的影响, 同时对SHS技术发展中存在问题进行了分析。

    Abstract:

    The development process of self-propagating high-temperature synthesis (SHS) at home and abroad was briefly summarized. The components of the element system of SHS precursor and the application direction of SHS products (powdered functional materials, ceramic materials, coating materials) were classified and expounded and the application of future energetic materials in SHS was emphatically analyzed. Secondly, the theoretical analysis of ignition mechanism, reaction mechanism, thermodynamics and kinetics of SHS materials suitable for different application directions was emphatically analyzed. On this basis, a new viewpoint that the adiabatic temperature was not the only criterion of SHS reaction was proposed. Finally, the combustion mechanism of SHS was introduced and the effects of experimental conditions such as particle sizes of reactants, milling parameters and pressed compact pressure of reactants on the SHS reactions were clarified. At the same time, the problems in the development of the SHS technology were analyzed.

    参考文献
    相似文献
    引证文献
文章指标
  • PDF下载次数:
  • HTML阅读次数:
  • 摘要点击次数:
  • 引用次数:
引用本文

左蓓璘,刘佩进,张维海,等.高温自蔓延反应合成功能材料的研究进展[J].含能材料, 2018, 26(6):537-544. DOI:10.11943/j. issn.1006-9941.2018.06.012.
ZUO Bei-lin, LIU Pei-jin, ZHANG Wei-hai, et al. Recent Progress on the Functional Materials Synthesized by High Temperature Self-Propagating Reactions[J]. Chinese Journal of Energetic Materials, 2018, 26(6):537-544. DOI:10.11943/j. issn.1006-9941.2018.06.012.

复制
历史
  • 收稿日期: 2017-11-10
  • 最后修改日期: 2018-02-21
  • 录用日期:
  • 在线发布日期: 2018-06-20
  • 出版日期: 2018-06-25