CHINESE JOURNAL OF ENERGETIC MATERIALS
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DNTF/RDX-CMDB推进剂低温力学性能
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(西安近代化学研究所, 陕西 西安 710065)

作者简介:

肖玮(1973-),男,工程师,主要从事火炸药力学性能研究。e-mail: liliangliang100@sohu.com

通讯作者:

李亮亮(1983-),男,工程师,主要从事火炸药力学性能研究。e-mail: liliangliang100@sohu.com

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Mechanical Properties for DNTF/RDX-CMDB Propellants at Low Temperature
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(Xi′an Modern Chemistry Research Institute, Xi′an 710065, China)

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    摘要:

    用单轴抗拉实验、动态力学分析仪和简支梁抗冲实验研究了不同3,4-二硝基呋咱基氧化呋咱(DNTF)/ RDX配比对DNTF/RDX改性双基(CMDB)推进剂(DNTF/RDX-CMDB,DFR推进剂)力学性能的影响。获得了-40 ℃下DFR推进剂的抗拉强度(σm)、断裂延伸率(εm)及抗冲强度(aK)。根据“时间-温度”等效原理的WLF方程获得了DFR推进剂β松弛阶段的动态特征量黏弹系数(C1g)。分析了组分含量对各力学性能的影响和σmεm的变化规律。结果表明:低温下的σmεmaK均与增塑剂含量间存在相关性。增塑剂含量减小,粘弹系数增加,NC分子侧基的“自由体积”下降,导致抗拉强度、断裂延伸率等力学性能降低。

    Abstract:

    Influence of different ratios of 1,3,5-trinitrohexahydrotriazine(RDX) to 3,4-bisnitrofurazan-furoxan(DNTF) on the mechanical properties of DNTF/RDX composite modified double-base(CMDB) propellant (DNTF/RDX-CMDB, DFR propellant) was studied by uniaxial tensile test, charpy impact test and dynamic mechanical analyzer.The tensile strength (σm), elongation at the maximum stress(εm) and impact strength(aK) of DFR propellant at -40 ℃ were obtained. The dynamical characteristics (viscoelastic coefficients C1g) of β -relaxation was acquired by WLF equation according to the "Time-Temperature" equivalence principle. The effect of plasticizer content on the various mechanical properties and change rule of σm and εm were analyzed, showing that a good correlation between σm, εm, aK at low temperature and plasticizer content. The plasticizer content reducing, C1g increasing, "free volume of side group of NC molecule" decreasing make the mechanical performances (σm and εm) worsen.

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引用本文

肖玮,李亮亮,王江宁,等. DNTF/RDX-CMDB推进剂低温力学性能[J].含能材料, 2013, 21(4):495-499.
XIAO Wei, LI Liang-liang, WANG Jiang-ning, et al. Mechanical Properties for DNTF/RDX-CMDB Propellants at Low Temperature[J]. Chinese Journal of Energetic Materials, 2013, 21(4):495-499.

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  • 收稿日期: 2012-09-24
  • 最后修改日期: 2012-11-14
  • 录用日期: 2013-01-09
  • 在线发布日期: 2013-08-29
  • 出版日期: