CHINESE JOURNAL OF ENERGETIC MATERIALS
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不敏感四唑非金属含能离子化合物的研究进展
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西安近代化学研究所,西安近代化学研究所,西安近代化学研究所,西安近代化学研究所,西安近代化学研究所,西安近代化学研究所,西安近代化学研究所

作者简介:

毕福强(1982-),男,工程师,博士生,主要从事含能材料的合成与性能研究。e-mail: bifuqiang@gmail.com

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国防科研基础计划项目(No. B09201100051) 


Review on Insensitive Non-metallic Energetic Ionic Compounds of Tetrazolate Anions
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Xi’an Modern Chemistry Research Institute,Xi’an Modern Chemistry Research Institute,Xi’an Modern Chemistry Research Institute,Xi’an Modern Chemistry Research Institute,Xi’an Modern Chemistry Research Institute,Xi’an Modern Chemistry Research Institute,Xi’an Modern Chemistry Research Institute

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    摘要:

    四唑非金属含能离子化合物是近年来逐渐发展起来的一类新型不敏感含能材料。综述了以氨基四唑、硝基四唑、硝氨基四唑、偶氮四唑和呋咱取代四唑为阴离子的不敏感非金属含能离子化合物的研究进展,结果表明,5位连有硝基和硝氨基等传统含能基团的四唑离子化合物的感度普遍较高,而以氨基四唑、偶氮四唑和4-氨基-3-(四唑基)呋咱为阴离子的含能化合物有望在不敏感含能材料领域得到广泛应用,并进而提出了不敏感四唑非金属含能离子化合物研究的发展方向。

    Abstract:

    Non-metallic energetic ionic compounds of tetrazolate anion are a kind of insensitive energetic materials. The progresses in the insensitive non-metallic energetic salts of aminotetrazolate, nitrotetrazolate, nitraminotetrazolate, azotetrazolate and furazan fuctionalized tetrazolate anions were reviewed in detail. It is found that most of ionic compounds based on tetrazolate anions which contain traditional energetic functionalities upon the carbon of positon 5 such as nitro and nitrimino functionalities, show high sensitivities, while the sensitivities of ionic compounds based on 5-aminotetrazolate, 5, 5′-azotetrazolate and 5-(4-aminofurazan-3-yl)tetrazolate are so low that they can be used as insensitive energetic materials. Furthermore, new trends in research of insensitive non-metallic energetic ionic compounds of tetrazolate anion were proposed.

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毕福强,樊学忠,许诚,等.不敏感四唑非金属含能离子化合物的研究进展[J].含能材料, 2012, 20(6):805-811. DOI:10.3969/j. issn.1006-9941.2012.06.031.
BI Fu-qiang, FAN Xue-zhong, XU Cheng, et al. Review on Insensitive Non-metallic Energetic Ionic Compounds of Tetrazolate Anions[J]. Chinese Journal of Energetic Materials, 2012, 20(6):805-811. DOI:10.3969/j. issn.1006-9941.2012.06.031.

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  • 收稿日期: 2011-09-27
  • 最后修改日期: 2012-03-03
  • 录用日期: 2012-05-02
  • 在线发布日期: 2012-12-25
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