CHINESE JOURNAL OF ENERGETIC MATERIALS
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烟火切割热力学分析及药剂配方设计与实验
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王鹏(1980-),男,博士,主要从事烟火切割技术研究。 e-mail: wang_peng@wjxy.edu.cn

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灭火救援技术公安部重点实验室开放课题资助项目(2009)


Thermo Dynamic Analysis, Composition Design and Experimental Study on Metal-Cutting Pyrotechnic Composition
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    摘要:

    从传热学和力学两方面分析了烟火切割的理论基础,重点分析了影响烟火切割效果的主要因素的原因和解决方法。考虑价格和毒性因素,应用化学热力学理论计算了烟火药的绝热反应温度,筛选出了放热充足的铝热剂。实验观察了铝热剂的燃烧,确定了适于烟火切割的两种铝热剂为由氧化铜组成的铜铝热剂和由三氧化二铁组成的铁铝热剂。通过均匀配方设计实验确定了烟火药的较佳配方,研究出了一种用于高温熔化金属材料的烟火药剂。主要由铁铝热剂30%~50%、铜铝热剂30%~50%和高热剂10%~20%组成。该烟火药燃烧时产生高温、高速、熔融态的铜铁合金射流,能有效地对金属材料进行切割。

    Abstract:

    The theory of pyrotechnic cutting was analyzed by heat transfer theory and mechanics, the reason and solution of the main influencing factor of pyrotechnic cutting effect were studied. Considering both price and toxicity, and the adiabatic reaction temperature of pyrotechnics was calculated by chemical thermodynamics, the thermites with adequate heat were screen out. By experimental observation of the combustion of thermites, two kinds of thermites that are appropriate for pyrotechnic cutting were determined, which are cupric thermite and ferric thermite. By uniform designed experiments, the good formula of pyrotechnics that is used for melting metal material was obtained. Which is composed of ferric thermite 30%~50%, cupric thermite 30%~50% and other thermite 10%~20%. The pyrotechnics can generate high temperature and high speed melting jet of Cu-Fe alloy, which can cut metal material effectively.

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王鹏,张靖.烟火切割热力学分析及药剂配方设计与实验[J].含能材料, 2011, 19(4):459-463. DOI:10.3969/j. issn.1006-9941.2011.04.024.
WANG Peng, ZHANG Jing. Thermo Dynamic Analysis, Composition Design and Experimental Study on Metal-Cutting Pyrotechnic Composition[J]. Chinese Journal of Energetic Materials, 2011, 19(4):459-463. DOI:10.3969/j. issn.1006-9941.2011.04.024.

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  • 收稿日期: 2010-09-28
  • 最后修改日期: 2011-05-20
  • 录用日期: 2010-11-26
  • 在线发布日期: 2012-02-22
  • 出版日期: