CHINESE JOURNAL OF ENERGETIC MATERIALS
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PGN/ADN推进剂的燃烧性能
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总装备部十一五预研课题资助项目(51328050501)


Combustion Properties of PGN/ADN Propellants
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    摘要:

    采用靶线法在3.0~15.0 MPa压强范围内,研究了固含量、铝粉含量、二硝酰胺铵(ADN)的粒径及含量、燃速调节剂及热稳定剂对PGN/ADN推进剂燃烧性能的影响。结果表明,ADN的粒径(<450 μm,450~900 μm)和含量(0%~30%)增加时,PGN/ADN推进剂的燃速和压强指数均适当增加; 改变Al粉含量,PGN/ADN推进剂的燃速和压强指数均无明显变化; 添加适量(0.5%)燃速调节剂Fe2O3可增加推进剂的燃速并降低压强指数,添加适量(0.5%)燃速调节剂草酰胺可有效降低压强指数。 添加适量稳定剂(1%)2-硝基二苯胺(2-DNPA)和N-甲基-4-硝基苯胺(MNA)可以使推进剂的压强指数分别由0.49降低到0.34和0.40。

    Abstract:

    By using the target-line method,the effects of solid content,aluminum content, ammonium dinitramide (ADN) content and particle size, burning rate catalyst and heat stabilizer on the combustion properties of PGN/ADN propellants were studied during the pressure from 3.0 MPa to 15.0 MPa. Results show that the burning rate of PGN/ADN propellants increases from 9.63 mm?s-1 to 26.71 mm?s-1, of which the pressure exponent increases from 0.49 to 1.05 when the diameter of ADN increases from less than 450 μm to 450-900 μm. On the other hand, the burning rate increases from 4.83 mm?s-1 to 12.18 mm?s-1, and the pressure exponent increases from 0.11 to 0.61 when the content of ADN increases from 0 to 30%. Aluminum had little effect on buring rate and pressure exponent. Burning rate increases 16.1% by adding Fe2O3 with 0.5% content. The pressure exponent drops to 0.22 by adding oxamide (OXM) with the same content as Fe2O3; simultaneously, the pressure exponent drops differently to 0.34 and 0.40 by adding 1% 2-nitrodiphenylamine (2-DNPA) and 1% N-methyl-4-nitroaniline (MNA) stabilizer separately.

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尚冬琴,黄洪勇. PGN/ADN推进剂的燃烧性能[J].含能材料, 2010, 18(4):372-376. DOI:10.3969/j. issn.1006-9941.2010.04.004.
SHANG Dong-qin,,HUANG Hong-yong. Combustion Properties of PGN/ADN Propellants[J]. Chinese Journal of Energetic Materials, 2010, 18(4):372-376. DOI:10.3969/j. issn.1006-9941.2010.04.004.

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  • 收稿日期: 2009-10-28
  • 最后修改日期: 2009-12-17
  • 录用日期: 2009-12-30
  • 在线发布日期: 2012-02-22
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