CHINESE JOURNAL OF ENERGETIC MATERIALS
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密度大于1的高密度液体碳氢燃料合成及复配研究
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教育部博士点新教师基金(200800561011)


Synthesis and Blending of High-density Hydrocarbon Fuels with Density Beyond 1.0 g·cm-3
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    摘要:

    以双环戊二烯为原料合成了三种高密度燃料组元C10、C15及C20,其密度依次增加,但低温性质逐渐变差。为制备密度大于1且低温性质良好的高密度燃料,进行二元及三元复配,建立了复配燃料密度及低温粘度与组成的关系。C10可显著改善燃料的低温性质,而C20则可提高燃料密度。确定了兼具高密度和低粘度的燃料组成区域:C15为主组分,C10含量低于25%,C20的含量低于10%。此组成的复配燃料密度大于1 g·cm-3 (15 ℃),净热值达42.0 MJ·L-1,粘度小于500 mm2·s-1 (-40 ℃),倾点小于-70 ℃,具有良好的应用前景。

    Abstract:

    Three high-density hydrocarbons with molecular structure of C10H16 (C10), C15H22 (C15) and C20H28 (C20) were synthesized using dicyclopentadiene as feedstocks. The density of the fuels increases in the order of C10,C15 and C20,whereas the low-temperature properties show the inverse tendency. To obtain higher density and acceptable low-temperature property,binary and ternary blendings of them were prepared. The dependence of density and viscosity on the composition of blends was analyzed,and an equation was established to predict the density of blendings. C10 can improve the low-temperature of blendings,whereas C20 can enhance the density. According to the density-viscosity-composition ternary diagrams,an optimized blending composition of C15≥75wt%,C20≤20wt% and C20≤5wt% was determined. The resulting fuel has density larger than 1.0 g·cm-3 (15 ℃),volume heat larger than 42.0 MJ·L-1,viscosity smaller than 500 mm2·s-1 (-40 ℃),and pour point smaller than -70 ℃, which is very promising for propulsion applications.

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王磊,张香文,邹吉军,等.密度大于1的高密度液体碳氢燃料合成及复配研究[J].含能材料, 2009, 17(2):157-160. DOI:10.3969/j. issn.1006-9941.2009.02.007.
WANG Lei, ZHANG Xiang-wen, ZOU Ji-jun, et al. Synthesis and Blending of High-density Hydrocarbon Fuels with Density Beyond 1.0 g·cm-3[J]. Chinese Journal of Energetic Materials, 2009, 17(2):157-160. DOI:10.3969/j. issn.1006-9941.2009.02.007.

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  • 收稿日期: 2008-09-04
  • 最后修改日期: 2008-11-21
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  • 在线发布日期: 2009-07-01
  • 出版日期: 2009-04-25