CHINESE JOURNAL OF ENERGETIC MATERIALS
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含肼废水的净化和肼回收装置的研究
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王煊军(1965-),男,博士后,教授,主要从事环境工程、火箭推进剂分析与检测的教学、科研与设计工作。

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Equipment for Purifying Wastewater Containing Hydrazine and Recovering Hydrazine
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    摘要:

    针对火箭推进剂无水肼在使用过程中产生的废水,提出以化学成盐的形式从高浓度含肼废水中回收硫酸肼,用Cu2+-双氧水催化氧化法处理低浓度含肼废水,并研制出国内首台移动式含肼废水的净化和肼回收装置。重点对温度、浓硫酸投加量、反应pH值等影响因素进行了研究,确立了硫酸肼回收工艺的正常运行参数。介绍了含肼废水净化和肼回收装置的基本原理、关键技术和运行情况。结果表明,系统运行稳定高效,硫酸肼回收产率可达90%以上,处理后出水达到国家污水排放标准。

    Abstract:

    The chemical methods of recycling the sulfuric hydrazine with a form of salt from the high concentration wastewater and purifying the low concentration wastewater by Cu2+-H catalytic oxidizing are proposed. The first domestic mobile equipment is developed to purify wastewater containing hydrazine and recover hydrazine. The operational parameters of recovering sulfuric hydrazine is determined, and the important factors such as temperature, concentrated sulfuric acid addition and pH value in reaction are studied. Furthermore, the fundamental principle, the key technique and the operational condition is introduced. The results show that the system works with stable condition and high availability, and the average recovery rate of sulfuric hydrazine reaches 90% over, the treated wastewater is up to the national disposal standard.

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王煊军,吴利刚,刘建才,等.含肼废水的净化和肼回收装置的研究[J].含能材料, 2005, 13(6):405-407.
WANG Xuan-jun, WU Li-gang, LIU Jian-cai, et al. Equipment for Purifying Wastewater Containing Hydrazine and Recovering Hydrazine[J]. Chinese Journal of Energetic Materials, 2005, 13(6):405-407.

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  • 收稿日期: 2005-02-28
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  • 在线发布日期: 2011-11-03
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