CHINESE JOURNAL OF ENERGETIC MATERIALS
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缩水甘油硝酸酯的一锅法合成(英)
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QIU Shao-jun(1971-),male,Ph. D. Research field: the synthesis and properties of functional materials. e-mail: qiu-shaojun@163.com

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One-pot Synthesis of Glycidyl Nitrate
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    摘要:

    环氧氯丙烷滴加到35%的稀硝酸中,于20 ℃左右进行开环反应,然后用氢氧化钠溶液进行关环反应,得到缩水甘油硝酸酯,得率为60%。用FTIR, 1H NMR, 13C NMR和元素分析对产物进行了结构表征。

    Abstract:

    A mild, low cost synthetic method of glycidyl nitrate is developed via so called one-pot procedure. Epichlorohydrin added dropwise to the dilute nitric acid (35 wt%) resulted in ring-opening reaction at about 20 ℃. Ring-closing occurred then by the addition of aqueous sodium hydroxide. Glycidyl nitrate was obtained in moderate yield (60%) and its structure was characterized by Fourier transform infrared spectroscopy, hydrogen and carbon nuclear magnetic resonance and elemental analysis.

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邱少君,甘孝贤,樊慧庆.缩水甘油硝酸酯的一锅法合成(英)[J].含能材料, 2005, 13(4):211-213.
QIU Shao-jun, GAN Xiao-xian, FAN Hui-qing. One-pot Synthesis of Glycidyl Nitrate[J]. Chinese Journal of Energetic Materials, 2005, 13(4):211-213.

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  • 收稿日期: 2005-01-18
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  • 在线发布日期: 2011-11-03
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