CHINESE JOURNAL OF ENERGETIC MATERIALS
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2,4,6,8,10,12-六硝基-2,4,6,8,10,12-六氮杂三环 [7·3·0·03.7]十二烷酮-5,11放热分解反应的动力学研究(英)
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ZHAO Feng-qi(1963-),male,professor,research fields: thermochemistry,thermal analysis and combustion property of energetic mareials. e-mail: npecc@21cn.com

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by the Science and Technology Foundation of Shaanxi Key Laboratory of Physico-inorganic Chemistry(No.29-3,2001) and the Science and Technology Foundation of the National Defense Key Laboratory of Propellant and Explosive Combustion of China(No.514550101,2003)


Kinetic Study on the Exothermic Decomposition Reaction of 2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazatricyclo[7·3·0·03.7]dodecane-5,11-dione
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    用DSC研究了标题化合物在线性升温条件下的热行为和放热分解反应的动力学参数。结果表明: 该反应的微分形式的经验动力学模式函数、表观活化能和指前因子分别为(1-α)-0.506, ,155.5 kJ·mol-1 和 1013.5 s-1 , 标题化合物的热爆炸临界温度为205.0 ℃。该反应的ΔS,ΔH和ΔG分别为6.0 J·mol-1·K-1, 146.5 kJ·mol-1 和 143.7 kJ·mol-1

    Abstract:

    Under linear temperature increase condition the thermal behavior and kinetic parameters of the exothermic decomposition reaction of the title compound were studied by means of DSC. The results show that the empirical kinetic model function in differential form, apparent activation energy and pre-exponential constant of this reaction are (1-α)-0.506, 155.5 kJ·mol-1 and 1013.5 s-1, respectively. The critical temperature of thermal explosion of the compound is 205.0 ℃. The values of ΔS, ΔH and ΔG of this reaction are 6.0 J·mol-1·K-1, 146.5 kJ·mol-1 and 143.7 kJ·mol-1, respectively.

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赵凤起,胡荣祖,杨得锁,等.2,4,6,8,10,12-六硝基-2,4,6,8,10,12-六氮杂三环 [7·3·0·03.7]十二烷酮-5,11放热分解反应的动力学研究(英)[J].含能材料, 2005, 13(1):29-32.
ZHAO Feng-qi, HU Rong-zu, YANG De-suo, et al. Kinetic Study on the Exothermic Decomposition Reaction of 2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazatricyclo[7·3·0·03.7]dodecane-5,11-dione[J]. Chinese Journal of Energetic Materials, 2005, 13(1):29-32.

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  • 收稿日期: 2004-09-08
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  • 在线发布日期: 2011-11-03
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