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含能材料的一种非等温反应动力学处理方法
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A TREATMENT METHOD OF NON-ISOTHERMAL REACTION KINETCS FOR ENERGETIC MATERIALS
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    摘要:

    提出了用非等温DSC曲线上的两个特征点的四个参数,求解含能材料的非等温反应动力学参数的两点法,定义了判别含能材料非等温DSC曲线的两个峰形抬数H。和τ,发现只有峰形指数同时满足0.1<H<1.0和1.8×10-2<τ<9.8×10-2时,该峰才可用动力学处理;给出了选择合理动力学参数及最可几机理函数的六条判断。用本文提出的两点法与其它八种常用的动力学处理方法进行了对比,给出了典型计算实例.

    Abstract:

    Two-point method was established to determine the non-isothermal reaction kinetic parameters of energetic materials by using four parameters from two characteristic points on the non-isothermaI DSC curve. Two peak indexes Hw and τw were defined to judge the non-isothermaI DSC curve of energetic materials.It was found that only when these indexes coincided with the conditions of 0.1≤Hw≤1.0 and 1.8×1O-2≤τm≤9.8× 1O-2,the peak could be treated with kinetics methods. Some empiric judgements were given for chosen the most probable mechanism function and the reasonable kinetics parameters.A typical computation example was listed to compare the two-point method with those commonly used in kinetics.

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张同来,胡荣祖,李福平.含能材料的一种非等温反应动力学处理方法[J].含能材料, 1994, 2(2):19-25.
Zhang Tong-lai, Hu Rong-zu, Li Fu-ping. A TREATMENT METHOD OF NON-ISOTHERMAL REACTION KINETCS FOR ENERGETIC MATERIALS[J]. Chinese Journal of Energetic Materials, 1994, 2(2):19-25.

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  • 收稿日期: 1993-12-23
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  • 在线发布日期: 2011-11-02
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