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基于临界半衰期的连续流反应热安全风险评估方法
作者:
作者单位:

1.华东理工大学反应安全中心, 上海 200237;2.中国工程物理研究院化工材料研究所, 四川 绵阳 621999

作者简介:

盛敏(1980-),男,讲席教授,博士生导师,研究方向为反应安全风险评估,反应动力学和锂电池热安全,E-mail:minsheng@ecust.edu.cn田均均(1987-),男,博士,副研究员,研究方向为单质炸药合成工艺放大研究,工艺工程安全评估研究,不敏感含能材料性能评估与应用研究,E-mail:junjun.tian@caep.cn

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基金项目:

国家重点研发计划资助(2023YFC3008700)


Thermal Safety Risk Assessment Method Based on Critical Reaction Half-life for Continuous Flow Reactors
Author:
Affiliation:

1.Reactive Chemical Safety Center, East China University of Science and Technology, Shanghai 200237, China;2.Institute of Chemical Materials, CAEP, Mianyang 621999, China

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    摘要:

    为了更好地评估连续流反应热安全风险,研究以通道式反应器为例,通过构建基于热量衡算和物料衡算的反应体系模型,对连续流反应体系的实际传热量和热安全风险进行了研究。针对通道式反应器进口端的绝热温升反应现象,提出了临界半衰期作为热安全判据的方法,获得了具有热安全高风险的两大反应条件,分别为:当目标反应产热总量大于800 J·g-1,且该反应在反应温度下半衰期小于临界半衰期;当分解反应产热总量大于800 J·g-1,且目标反应在反应温度下半衰期小于临界半衰期,同时分解反应在100%MTSR(工艺反应能够达到的最高温度)下半衰期也小于临界半衰期。并且通过氯苯硝化反应验证其准确性和实用性,结果显示,通道式反应器在该条件下可发生分解爆炸反应,证实了该评估方法可用于确定连续流反应热安全的高风险条件。

    Abstract:

    To better evaluate the thermal safety risk of continuous flow reactions, a study was conducted using a tubular reactor as an example. By constructing a reaction system model based on heat balance and material balance, the actual heat transfer and thermal safety risk of continuous flow reaction systems were investigated. To address the adiabatic temperature rise reaction phenomenon at the inlet end of a channel reactor, a method based on the critical reaction half-life was proposed as a criterion for thermal safety assessment. Two major reaction conditions with high thermal safety risk were identified: when the total heat release of the target reaction is greater than 800 J·g-1, and the reaction half-life of the reaction at the reaction temperature is less than the critical reaction half-life; when the total heat release of the decomposition reaction is greater than 800 J·g-1, and the reaction half-life of the target reaction at the reaction temperature is less than the critical reaction half-life, while the reaction half-life of the decomposition reaction at 100% MTSR(maximum temperature that the process reaction can reach) is also less than the critical reaction half-life.Furthermore,the accuracy and practicality were verified through the nitration reaction of chlorobenzene,and the results show that an explosively decomposition reaction could occur in the channel reactor under these conditions,thus confirming the high-risk thermal safety conditions of continuous flow reactions determined by this evaluation method.

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引用本文

盛敏,田均均,王芳芳,等.基于临界半衰期的连续流反应热安全风险评估方法[J].含能材料, 2024, 32(3):298-311. DOI:10.11943/CJEM2024018.
SHENG Min, TIAN Jun-jun, WANG Fang-fang, et al. Thermal Safety Risk Assessment Method Based on Critical Reaction Half-life for Continuous Flow Reactors[J]. Chinese Journal of Energetic Materials, 2024, 32(3):298-311. DOI:10.11943/CJEM2024018.

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历史
  • 收稿日期: 2024-01-13
  • 最后修改日期: 2024-02-17
  • 录用日期: 2024-02-05
  • 在线发布日期: 2024-02-07
  • 出版日期: 2024-03-25