3-氨基4-(叠氮乙酰胺基)呋咱合成
2002,10(3):112-113
中国科学院上海有机化学研究所, 上海 200032
摘要:
以3,4-二氨基呋咱(DAF)分别和氯乙酰氯、溴乙酰溴缩合得到了单取代乙酰化产物, 进一步叠氮化得到的3-氨基-4-(叠氮乙酰胺基)呋咱为高氮含量的呋咱含能衍生物。
关键词:
3,4-二氨基呋咱(DAF); 乙酰化; 叠氮化
Synthesis of 3-Amino-4-(azidoacetamido)Furazan
Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032,China
Abstract:
The acetylation of 3,4-diaminofurazan (DAF) was studied in this paper. By the reaction of DAF with chloroacetyl chloride and bromoacetyl bromide respectively, the substituted acetyl furazano derivatives were obtained. Then 3-amino-4-(azidoacetamido)furazan was obtained as an high nitrogen content furazano energetic derivative by treating these two intermediates with sodium azide.
KeyWord:
3,4-diaminofurazan; acetylation; azidation
投稿时间: 2002-04-17