CHINESE JOURNAL OF ENERGETIC MATERIALS
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芳族降速剂对HMX-CMDB推进剂燃烧性能的影响
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1山西北方兴安化学工业有限公司,山西 太原 030008;2大连理工大学力学与航空航天学院,辽宁 大连 116024;3中国科学院上海有机化学研究所,上海 200032

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Effect of Aromatic Burning Rate Inhibitor on the Combustion Performance of HMX-CMDB Propellants
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1Shanxi North Xing’an Chemical Industry Co. Ltd, Taiyuan 030008, China;2School of Mechanics and Aerospace Engineering, Dalian University of Technology, Dalian 116024, China;3Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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    摘要:

    为了探索芳族化合物对CMDB推进剂燃烧性能的影响,使用2,2"-(丙烷-1,1-二亚基)双(4-叔丁基苯酚)(2,2"-(propane-1,1-diyl)bis(4-(tert-butyl)phenol),PDBP)作燃速调节剂制备了HMX-CMDB推进剂,并使用靶线法对不同PDBP含量的HMX-CMDB推进剂燃烧性能进行了研究,结果表明:随着PDBP含量增加,HMX-CMDB推进剂燃速和压强指数显著下降。含7%PDBP的HMX-CMDB推进剂在16 MPa下燃速降低至8.55 mm·s-1,压强指数降低至0.217。相较传统降速剂蔗糖八醋酸酯(SOA),含等质量PDBP的HMX-CMDB在低压区(8~10 MPa)的燃速基本保持不变,在高压区(12~16 MPa)的燃速进一步降低,压强指数更低。此外,1%的PDBP替代SOA后,HMX-CMDB的爆热仅降低20 kJ·kg-1。通过化学结构分析,PDBP的降速作用机理为:分子热分解后形成质子与具有共轭 π 键结构的稳定自由基分子,活泼的质子能够与HMX-CMDB推进剂中含能分子分解出的活性自由基反应形成稳定结构,减缓自由基的自催化速率,达到降低燃速的作用。

    Abstract:

    In order to explore the effect of aromatic compounds on the combustion performance of CMDB propellant, 2,2"-(propane-1,1-diyl)bis(4-(tert-butyl)phenol) (PDBP) was used to prepare HMX-CMDB propellant, and the combustion performance of HMX-CMDB propellants with different PDBP contents was studied using the target line method. The results showed that with the increase of PDBP content, the burning rate and pressure index of HMX-CMDB propellant significantly decreased. For HMX-CMDB propellant containing 7% PDBP, the burning rate at 16 MPa decreased to 8.55 mm·s-1, and the pressure index decreased to 0.217. Compared with the sucrose octaacetate (SOA), HMX-CMDB propellant containing the same mass of PDBP exhibited almost unchanged burning rate in the low-pressure region (8-10 MPa), a further reduced burning rate in the high-pressure region (12-16 MPa), resulting in a lower pressure index. In addition, after replacing SOA with 1% PDBP, the detonation heat of HMX-CMDB propellant was reduced by only 20 kJ/kg. Based on chemical structure analysis, the mechanism of PDBP"s burning rate inhibition effect is as follows: the aromatic molecule decompose to form protons and structurally stable radical molecules with conjugated π bonds, and the active protons can react with the active radicals released from the decomposition of energetic molecules in the HMX-CMDB propellant, forming stable structures that mitigate the autocatalytic effect of free radicals, thereby reducing the burning rate.

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巩如楠,程国荣,赵卓安,等. 芳族降速剂对HMX-CMDB推进剂燃烧性能的影响[J]. 含能材料,DOI:10.11943/CJEM2026005.

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  • 收稿日期: 2026-01-06
  • 最后修改日期: 2026-04-09
  • 录用日期: 2026-04-02
  • 在线发布日期: 2026-04-07
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