CHINESE JOURNAL OF ENERGETIC MATERIALS
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热老化复合改性双基推进剂变温松弛模量模型研究
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陆空基信息感知与控制全国重点实验室

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Research on the Temperature-dependent Relaxation Modulus Model for Thermally Aged Composite Modified Double-base Propellants
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National Key Laboratory of Land and Air Based Information Perception and Control, Xi′an Modem Control Technology Research Institute, Xi′an 710065,China

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    为提升固体发动机装药长期贮存性能评估的准确性,解决现有模型难以同时耦合温度与老化时间效应的关键问题,实现宽温域、全老化周期内松弛模量的高精度预测。基于复合改性双基推进剂在343.15 K下加速老化实验获取的应力松弛数据,应用时间-温度等效原理,通过引入老化时间作为内变量,构建了考虑老化效应的变温松弛模量模型。模型结果表明,在233.15~323.15 K的测试温度范围内,以及343.15 K高温加速老化0~100 d的条件下,模型预测曲线与实验数据均呈现良好的一致性,说明该模型能够有效反映CMDB推进剂松弛模量在宽温域和全老化周期内的变化规律。

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    To improve the accuracy of long-term storage performance evaluation for solid rocket motor grains and solve the critical limitation of existing models being difficult to simultaneously couple the effects of temperature and aging time, this investigation aims to achieve high-precision prediction of relaxation modulus over a wide range of temperature and the full aging cycle. Based on the stress relaxation data obtained from accelerated aging tests of Composite Modified Double-Base(CMDB) propellant at 343.15 K, a temperature-dependent relaxation modulus model that accounts for aging effects was developed by applying the time-temperature equivalence principle and introducing aging time as an internal variable. The results show that the predicted curves are in good agreement with the experimental data under test temperatures ranging from 233.15 K to 323.15 K and after accelerated aging at 343.15 K for 0-100 days. Thus, it indicates that the developed model can effectively describe the variation of the relaxation modulus for CMDB propellant over a wide range of temperature and the full aging cycle.

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刘家铭,杨保雨,朱亮,等.热老化复合改性双基推进剂变温松弛模量模型研究[J].含能材料, 2026, 34(2):146-153. DOI:10.11943/CJEM2025233.
LIU Jia-ming, YANG Bao-yu, ZHU Liang, et al. Research on the Temperature-dependent Relaxation Modulus Model for Thermally Aged Composite Modified Double-base Propellants[J]. Chinese Journal of Energetic Materials, 2026, 34(2):146-153. DOI:10.11943/CJEM2025233.

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历史
  • 收稿日期: 2025-10-18
  • 最后修改日期: 2026-02-04
  • 录用日期: 2025-12-22
  • 在线发布日期: 2026-02-04
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